娌夋穩婧惰В骞宠 鏇茬嚎
娌夋穩婧惰В骞宠 鍥惧儚棰樼殑瑙ｉ绛栫暐
1
锛?/p>
娌夋穩婧惰В骞宠 鏇茬嚎绫讳技浜庢憾瑙ｅ害鏇茬嚎锛?/p>
鏇茬嚎涓婁换涓�鐐归兘琛ㄧず楗卞拰婧舵恫锛?/p>
鏇茬嚎涓婃柟鐨勪换涓�鐐瑰潎琛ㄧず杩囬ケ鍜屾憾娑诧紝
姝ゆ椂鏈夋矇娣�鏋愬嚭锛屾洸绾夸笅鏂圭殑浠讳竴鐐瑰潎琛ㄧず涓嶉ケ鍜屾憾娑层�?/p>
2
锛庝粠鍥惧儚涓壘鍒版暟鎹紝鏍规嵁
K
sp
鍏紡璁＄畻寰楀嚭
K
sp
鐨勫�笺�?/p>
3
锛庢瘮杈冩憾娑茬殑
Q
c
涓?/p>
K
sp
鐨勫ぇ灏忥紝鍒ゆ柇婧舵恫涓湁鏃犳矇娣�鏋愬嚭銆?/p>
4
锛庢秹鍙?/p>
Q
c
鐨勮绠楁椂锛屾墍浠ｅ叆鐨勭瀛愭祿搴︿竴瀹氭槸娣峰悎婧舵恫涓殑绂诲瓙娴撳害锛屽洜姝よ绠楃瀛愭祿搴︽椂锛屾墍浠ｅ叆鐨勬憾娑蹭綋
绉篃蹇呴』鏄贩鍚堟憾娑茬殑浣撶Н銆?/p>
1
锛庡湪
t
鈩冩椂锛?/p>
AgBr
鍦ㄦ按涓殑娌夋穩婧惰В骞宠 鏇茬嚎濡傚浘鎵�绀恒�傚張鐭?/p>
t
鈩冩椂
AgCl
鐨?/p>
K
sp
锛?/p>
4
脳
10
锛?/p>
10
锛屼笅鍒楄娉曚笉姝ｇ‘鐨?
鏄?/p>
(
)
A
锛庡湪
t
鈩冩椂锛?/p>
AgBr
鐨?/p>
K
sp
涓?/p>
4.9
脳
10
锛?/p>
13
B
锛庡湪
AgBr
楗卞拰婧舵恫涓姞鍏?/p>
NaBr
鍥轰綋锛屽彲浣挎憾娑茬敱
c
鐐瑰彉鍒?/p>
b
鐐?/p>
C
锛庡浘涓?/p>
a
鐐瑰搴旂殑鏄?/p>
AgBr
鐨勪笉楗卞拰婧舵恫
D
锛庡湪
t
鈩冩椂锛?/p>
AgCl(s)
锛?/p>
Br
锛?
(aq)
AgBr(s)
锛?/p>
Cl
锛?
(aq)
鐨勫钩琛″父鏁?/p>
K
鈮?/p>
816
绛旀
B
瑙ｆ瀽
鏍规嵁鍥句腑
c
鐐圭殑
c(Ag
锛?
)
鍜?/p>
c(Br
锛?
)
鍙緱璇ユ俯搴︿笅
AgBr
鐨?/p>
K
sp
涓?/p>
4.9
脳
10
锛?/p>
13
锛?/p>
A
姝ｇ‘锛涘湪
AgBr
楗卞拰婧舵恫涓姞
鍏?/p>
NaBr
鍥轰綋鍚庯紝
c(Br
锛?
)
澧炲ぇ锛屾憾瑙ｅ钩琛￠�嗗悜绉诲姩锛?/p>
c(Ag
锛?
)
鍑忓皬锛屾晠
B
閿欙紱鍦?/p>
a
鐐规椂
Q
c
锛?/p>
K
sp
锛屾晠涓?/p>
AgBr
鐨勪笉楗卞拰
婧舵恫锛?/p>
C
姝ｇ‘锛涢�夐」
D
涓?/p>
K
锛?/p>
c(Cl
锛?
)/c(Br
锛?
)
锛?/p>
K
sp
(AgCl)/K
sp
(AgBr)
锛屼唬鍏ユ暟鎹緱
K
鈮?/p>
816
锛?/p>
D
姝ｇ‘銆?/p>
2
锛庡凡鐭?/p>
25
鈩冩椂锛?/p>
CaSO
4
鍦ㄦ按涓殑娌夋穩婧惰В骞宠 鏇茬嚎濡傚浘鎵�绀猴紝鍚?/p>
100mL
璇ユ潯浠朵笅鐨?/p>
CaSO
4
楗卞拰婧舵恫涓姞鍏?/p>
400mL0.01mol路L
锛?/p>
1
Na
2
SO
4
婧舵恫锛屼笅鍒楀彊杩版纭殑鏄?/p>
(
)
A
锛庢憾娑蹭腑鏋愬嚭
CaSO
4
鍥轰綋娌夋穩锛屾渶缁堟憾娑蹭腑
c(SO
2
锛?
4
)
姣斿師鏉ョ殑澶?/p>
B
锛庢憾娑蹭腑鏃犳矇娣�鏋愬嚭锛屾憾娑蹭腑
c(Ca
2
锛?
)
銆?/p>
c(SO
2
锛?
4
)
閮藉彉灏?/p>
C
锛庢憾娑蹭腑鏋愬嚭
CaSO
4
鍥轰綋娌夋穩锛屾憾娑蹭腑
c(Ca
2
锛?
)
銆?/p>
c(SO
2
锛?
4
)
閮藉彉灏?/p>
D
锛庢憾娑蹭腑鏃犳矇娣�鏋愬嚭锛屼絾鏈�缁堟憾娑蹭腑
c(SO
2
锛?/p>
4
)
姣斿師鏉ョ殑澶?/p>
绛旀
D
瑙?/p>
鏋?/p>
鐢?/p>
鍥?/p>
鍍?/p>
鍙?/p>
鐭?/p>
K
sp
(CaSO
4
)
锛?/p>
9.0
脳
10
锛?/p>
6
锛?/p>
褰?/p>
鍔?/p>
鍏?/p>
400mL0.01mol路L
锛?/p>
1
Na
2
SO
4
婧?/p>
娑?/p>
鏃?/p>
锛?/p>
姝?/p>
鏃?/p>
c(Ca
2
锛?
)
锛?
3.0
脳
10
锛?/p>
3
mol路L
锛?/p>
1
脳
0.1L
0.5L
锛?/p>
6
脳
10
锛?/p>
4
mol路L
锛?/p>
1
锛?/p>
c(SO
2
锛?
4
)
锛?/p>
3.0
脳
10
锛?/p>
3
mol路L
锛?/p>
1
脳
0.1L
锛?.01mol路L
锛?/p>
1
脳
0.4L
0.5L
锛?/p>
8.6
脳
10
锛?/p>
3
mol路L
锛?/p>
1
锛?/p>
Q
c
锛?/p>
5.16
脳
10
锛?/p>
6
<K
sp
(CaSO
4
)
锛屾墍浠ユ憾娑蹭腑鏃犳矇娣�鏋愬嚭锛屼絾鏈�缁堟憾娑蹭腑
c(SO
2
锛?
4
)
姣斿師鏉ュぇ銆?/p>