澶у鏈夋満鍖栧缁撴瀯鎺ㄦ柇璇曞嵎锛?/p>
A
锛?/p>
鐝骇
濮撳悕
鍒嗘暟
涓夈�佹帹缁撴瀯棰?/p>
(
鍏?/p>
1
棰?/p>
4
鍒?/p>
)
99.
4
鍒?/p>
(1904)
1904
鍖栧悎鐗╁叚姘姮
(A)
鍜屽寲瀛﹀悕绉颁负浜?/p>
(2,3,5-
涓夋隘
-6-
缇熷熀鑻熀
)
鐢茬兎
,
骞挎硾鐢ㄤ簬鑲ョ殏銆?/p>
鍘昏嚟鍓?/p>
鍜屽叾瀹冨寲濡嗗搧鐨勬潃鑿屽墏銆傚寲鍚堢墿浜?/p>
(2,3,5-
涓夋隘鑻哀鍩?/p>
)
鐢茬兎
(B)
鍜屽寲鍚堢墿
A
鏈夌浉鍚岀殑鍒嗗瓙寮?/p>
,
鑰?/p>
B
鏄?/p>
灞?/p>
浜?/p>
(
)
绫?/p>
鍖?/p>
鍚?/p>
鐗?/p>
銆?/p>
鍥?/p>
鑰?/p>
鍖?/p>
鍒?/p>
A
鍜?/p>
B
鐨?/p>
鍖?/p>
瀛?/p>
鏂?/p>
娉?/p>
鍙?/p>
鍒?/p>
鐢?
(
), B
浼氬彂鐢熸按瑙ｇ敓鎴愭湁杩樺師鎬х殑鐢查啗鍒嗗瓙銆?/p>
涓�銆佹帹缁撴瀯棰?/p>
(
鍏?/p>
88
棰?/p>
560
鍒?/p>
)
1.
4
鍒?/p>
(3001)
3001
鍖栧悎鐗?/p>
C
2
H
6
O
鐨?/p>
NMR
璋卞彧鏈変竴涓崟宄?/p>
,
璇曟帹鍑哄叾鍙兘鐨勭粨鏋勫紡銆?/p>
2.
4
鍒?/p>
(3002)
3002
鍖栧悎鐗?/p>
C
3
H
6
Cl
2
鐨?/p>
1
H NMR
璋辨湁涓�涓崟宄?/p>
,
璇曟帹鍑哄叾鍙兘鐨勭粨鏋勫紡銆?/p>
3.
4
鍒?/p>
(3003)
3003
鍖栧悎鐗?/p>
C
3
H
6
O
鐨?/p>
NMR
璋辨湁涓�涓崟宄?/p>
,
璇曟帹鍑哄叾鍙兘鐨勭粨鏋勫紡
C
3
H
6
O
銆?/p>
4.
4
鍒?/p>
(3004)
3004
鍖栧悎鐗?/p>
C
4
H
6
O
2
鍦?/p>
1721cm
-1
鏄剧ず涓�涓緢寮虹殑鍚告敹甯?/p>
,
瀹冪殑
NMR
璋卞彧鏈変竴涓崟宄?/p>
,
璇曟帹鏂叾
缁撳紡
:
5.
6
鍒?/p>
(3005)